Journal
CHEMICAL REVIEWS
Volume 116, Issue 15, Pages 8848-8872Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.6b00043
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Funding
- FIRENZE HYDROLAB 2 project (Ente Cassa di Risparmio di Firenze)
- Premiale project Energia da fonti rinnovabili (MIUR, Rome)
- CNR-RFBR Italy-Russian Federation bilateral project of the Italian National Research Council
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This review is a comprehensive survey of the last 10 years of research on ammonia borane and amine borane dehydrogenation mediated by complex metal hydrides (CMHs), within the broader context of chemical hydrogen storage. The review also collects those cases where CMHs are the catalyst spent form or its resting state. Highlights on the reaction mechanism (strictly dependent on the CMH of choice) and the catalysts efficiency (in terms of equivalents of H-2 produced and relative reaction rates) are provided throughout the discussion.
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