Journal
CHEMICAL RECORD
Volume 16, Issue 6, Pages 2772-2786Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201600089
Keywords
aldehydes; ketones; nitrogen heterocycles; transfer hydrogenation; water chemistry
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Funding
- DTI MMI project
- EPSRC
- Pfizer
- AstraZeneca
- University of Liverpool
- National Natural Science Foundation of China [21473109, 21103102]
- Cheung Kong Scholar Program
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This article provides an account of our group's efforts in developing aqueous-phase transfer hydrogenation reactions. It is comprised of mainly two parts. The first part concentrates on asymmetric transfer hydrogenation in water, enabled by Noyori-Ikariya catalysts, while the second part is concerned with the achiral version of the reaction catalysed by a new class of catalysts, iridacycles. A range of substrates are featured, including various carbonyl compounds and N-heterocycles.
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