Journal
CHEMICAL RECORD
Volume 16, Issue 6, Pages 2754-2771Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201600100
Keywords
asymmetric catalysis; dynamic kinetic resolution; hydrogenation; transfer hydrogenation; total synthesis
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Funding
- CNRS (Centre National de la Recherche Scientifique)
- MENESR (Ministere de l'Education nationale, and de l'Enseignement superieur et de la Recherche)
- ANR (French National Research Agency)
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Over the last few decades, the development of new and highly efficient synthetic methods to obtain chiral compounds has become an increasingly important and challenging research area in modern synthetic organic chemistry. In this account, we review recent work from our laboratory toward the synthesis of valuable chiral building blocks through transition-metal-catalyzed asymmetric hydrogenation and transfer hydrogenation of C=O, C=N and C=C bonds. Application to the synthesis of biologically relevant products is also described.
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