4.6 Article

Fast transport of water molecules across carbon nanotubes induced by static electric fields

Journal

CHEMICAL PHYSICS LETTERS
Volume 644, Issue -, Pages 201-204

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2015.11.061

Keywords

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Funding

  1. National Natural Science Foundation of China [11547132]
  2. Natural Science Foundation of Anhui Province of China [1508085QA19, 1508085QA22]
  3. China Anhui Province Higher Education Promotion Plan [TSKJ2014B23]

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Water permeation across a single-walled carbon nanotube has been studied in the presence of static electric fields (SEFs) with different directions under hydrostatic pressures. With the angle between the SEF direction and tube axis increasing from 0 degrees to 90 degrees, the water flux decreases gradually until almost vanishes, and the maximum value at 0 degrees is approximately four times the case without SEFs. The phenomenon is attributed to the alignment of the polar water molecules along the SEF direction. We also show that water permeation properties are dependent on the field strength due mainly to thermal fluctuations of water molecules. (C) 2015 Elsevier B.V. All rights reserved.

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