Journal
NANOTECHNOLOGY
Volume 31, Issue 29, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/1361-6528/ab8667
Keywords
oxygen evolution reaction; one-dimensional nanostructures; nanowire; NiCo2Se4; water splitting
Funding
- 'Human Resources Program in Energy Technology' of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) from Ministry of Trade, Industry & Energy, Republic of Korea [20174030201760]
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2019R1I1A3A01046928]
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Oxygen evolution reaction (OER), a sluggish multistep process in electrochemical water splitting, is still a challenging issue to achieve with cheap, earth-abundant non-precious and non-polluting materials. In this work, three different electrocatalysts, specifically NiCo2O4, NiCo2 S-4, and NiCo2 Se-4,Se- synthesized by simple hydrothermal process, show excellent OER activity. This report not only projects OER performances but also demonstrates a modified method for the transformation of NiCo2O4 to NiCo2 S-4 and NiCo2 Se-4 via sulfidation and selenization reactions. The well crystalline, porous nature of NiCo2O4, NiCo2 S-4, and NiCo2Se4 electrocatalysts with one dimensional (1D) structural morphology affords overpotentials of 346 mV, 309 mV and 270 mV at current density of 10 mA cm(-2) in 1 M KOH. In particular, NiCo2Se4 exhibits a low overpotential as well as a smaller Tafel slope of 63 mV dec(-1), leading to robust stability in alkaline conditions. The abundant active sites, large mass and size of NiCo2Se4 enhances the performance of the OER. This type of selenide-based material with low toxicity is also an advantage for eco-friendly applications.
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