Journal
CHEMICAL PHYSICS LETTERS
Volume 658, Issue -, Pages 315-318Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2016.06.056
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Funding
- IISc
- DST
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In most template directed preparative methods, while the template decides the nanostructure morphology, the structure of the template itself is a non-general outcome of its peculiar chemistry. Here we demonstrate a template mediated synthesis that overcomes this deficiency. This synthesis involves overgrowth of silica template onto a sacrificial nanocrystal. Such templates are used to copy the morphologies of gold nanorods. After template overgrowth, gold is removed and silver is regrown in the template cavity to produce a single crystal silver nanorod. This technique allows for duplicating existing nanocrystals, while also providing a quantifiable breakdown of the structure - shape interdependence. (C) 2016 Elsevier B.V. All rights reserved.
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