Collisional excitation of H2S by molecular hydrogen

Accurate estimates of the abundance of H2S, and inferences about the unmeasured H-2 density, require accurate knowledge of radiative and collisional rate coefficients. Time-independent close-coupling quantum scattering calculations have been employed to compute rate coefficients for (de-)excitation of para- and ortho-H2S in collisions with para- and ortho-H-2. These calculations utilized a potential energy surface for the interaction of H2S with H-2 recently computed by the explicitly correlated CCSD(T)-F12a coupled-cluster method. Rate coefficients for temperatures ranging from 5 to 500K were calculated for all transitions among the first 19 rotational levels of H2S, whose energies are less than or equal to 405 K. These rate coefficients are compared with previous estimates of these quantities.