Journal
MOLECULES
Volume 25, Issue 9, Pages -Publisher
MDPI
DOI: 10.3390/molecules25092116
Keywords
electrophilic fluorination; hydrogen fluoride; hypervalent iodine; fluorination reagents; bioactive compounds
Funding
- National Natural Science Foundation of China [21761132021]
- IKERBASQUE, Basque Foundation for science
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This review article focused on the innovative procedure for electrophilic fluorination using HF and in situ generation of the required electrophilic species derived from hypervalent iodine compounds. The areas of synthetic application of this approach include fluorination of 1,3-dicarbonyl compounds, aryl-alkyl ketones, styrene derivatives, alpha,beta-unsaturated ketones and alcohols, homoallyl amine and homoallyl alcohol derivatives, 3-butenoic acids and alkynes.
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