Journal
MOLECULES
Volume 25, Issue 7, Pages -Publisher
MDPI
DOI: 10.3390/molecules25071503
Keywords
nitronyl nitroxides; iminonitroxides; diradicals; pyrrole derivatives; magnetochemistry; quantum-chemical calculations
Funding
- Russian Science Foundation [18-13-00173]
- Russian Foundation for Basic Research [19-29-08005]
- Russian Science Foundation [18-13-00173] Funding Source: Russian Science Foundation
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In contrast to diradicals connected by alternant hydrocarbons, only a few studies have addressed diradicals connected by nonalternant hydrocarbons and their heteroatom derivatives. Here, the synthesis, structure, and magnetic properties of pyrrole-2,5-diyl-linked bis(nitronyl nitroxide) and bis(iminonitroxide) diradicals are described. The diradicals show characteristic electron spin resonance spectra in dilute glassy solutions, from which conclusions about the presence of distinct conformations, their symmetry, and interspin distance were made. X-ray diffraction analysis of the diradicals revealed that paramagnetic moieties lie in the plane of the pyrrole ring, because of the formation of an intramolecular hydrogen bond, O-NO...H-N, with O...H distances of 2.15-2.23 angstrom. The N-O groups participating in the formation of H-bonds have greater bond lengths (1.29 angstrom) as compared with nonparticipating groups (1.27 angstrom). The nitronyl nitroxide and iminonitroxide diradicals showed an intramolecular antiferromagnetic interaction, with J = -77.3 and -22.2 cm(-1), respectively (H = -2JS(1).S-2).
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