4.7 Article

Silver-polymer nanocomposites: Structural, thermal and electromechanical elucidation for charge storage applications

Journal

MEASUREMENT
Volume 156, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.measurement.2020.107615

Keywords

Silver-PVA nanocomposites; Ionic conductivity; Mechanical properties; X-ray diffraction (XRD); Atomic force microscopy (AFM)

Funding

  1. Higher Education Commission (HEC) of Pakistan

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PVP stabilized Silver nanoparticles were synthesized and were used to prepare different compositions of polymer nanocomposites using poly (vinyl alcohol) as a polymer matrix. AC impedance spectroscopy, tensile testing (tensile strength, Young's modulus, elongation at break), atomic force microscopy (AFM), X-Ray diffraction (XRD), Thermogravimetric analysis (TGA/DTA) and Scanning Electron Microscopy (SEM) were used to characterize the prepared nanocomposite samples. Through this communication, we are reporting a much-enhanced electrical conductivity and mechanical properties of the nanocomposite films. The AFM and SEM propose a smooth surface morphology with uniformly dispersed nanoparticles. A fairly controlled size and uniform morphology discloses that PVP has played its role in controlling the diameter and dispensability of the nanoparticles. The outcome of the XRD suggests a semi crystalline structure of XRD results suggest that the prepared nanocomposite exhibits the semicrystalline nature. Thermal analysis depicts that the thermal stability enhances as a function of the silver nanoparticles. (C) 2020 Elsevier Ltd. All rights reserved.

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