Journal
MATERIALS LETTERS
Volume 265, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.matlet.2020.127464
Keywords
Physical vapour deposition; Thin films; Electrochromic device; All-solid-state; Fast response; wO(3)
Funding
- National Natural Science Foundation of China [51572058, 51502057]
- National Key Research & Development Program [2016YFB0303903, 2016YFE0201600]
- International Science & Technology Cooperation Program of China [2013DFR10630, 2015DFE52770]
- Foundation of Equipment Development Department [622091401090]
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In this study, all-solid-state electrochromic device (ECD) with a novel four-layered structure of glass/ITO/Li-NiO/Li-WO3/ITO was prepared by e-beam and resistive heating evaporation. Tungsten oxide (WO3), nickel oxide (NiO) and indium tin oxide (ITO) were used as electrochromic layer, complementary layer and electrode layer, respectively. Lithium was used as electrolyte ion and evaporated on the complementary layer directly, replacing the normally used independent electrolyte layer. Since the lithium ions can transfer between WO3 and NiO layer directly during the electrochromic process, the ECD shows a fast response speed with coloring and bleaching time of 8.6 s and 1.7 s, respectively, due to the reduction of the overall resistance of the device. The unique structure of ECD may further advance the development in the practical applications. (C) 2020 Elsevier B.V. All rights reserved.
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