Journal
MACROMOLECULES
Volume 53, Issue 7, Pages 2582-2593Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.9b02485
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Funding
- Ministry of Research and Education of the Russian Federation [14.W03.31.0022]
- National Science Foundation [DMR 1407645, DMR 1921835]
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We present an analytical theory of microphase separation in the melt of bottlebrush and comblike block copolymers in the strong segregation limit. The constructed phase diagram predicts morphologies and dimensions of the microsegregated domains as a function of molecular masses of both blocks, grafting densities and lengths of side chains in the comblike and bottlebrush blocks. The theoretical predictions are corroborated by experimental data.
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