Journal
CHEMICAL ENGINEERING JOURNAL
Volume 306, Issue -, Pages 193-203Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2016.07.057
Keywords
All solid-state asymmetric supercapacitor; NiO nanosheet; alpha-Fe2O3 nanorod; Low-cost; Long cycle life
Categories
Funding
- National Natural Science Foundation of China [21273058]
- China Postdoctoral Science Foundation [2012M520731]
- Heilongjiang Postdoctoral Financial Assistance [LBH-Z12089]
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Through a facile hydrothermal method at a mild temperature and a calcination process, we report the fabrication about the NiO nanosheets and alpha-Fe2O3 nanorods using nickel foam (NF) and carbon cloth (CC) as substrates. Analysis of data obtained from the electrochemical experiments show that NiO electrode possesses large areal capacitance (1.3 F cm(-2) at 4 mA cm(-2)). Also, alpha-Fe2O3 electrode delivers areal capacitance of 500 mF cm(-2) at current density of 4 mA cm(-2). Therefore, a high-performance all solid-state asymmetric supercapacitor (ASC) based on 3D sheet-like hierarchical NiO and alpha-Fe2O3 nanorods are designed and fabricated. New ASC can be cycled reversibly in a high voltage region ranging from 0 to 1.25 V with high energy densities of 12.4 W h kg(-1) (power is 951 W kg(-1)) based on the total mass of active materials. Furthermore, the obtained data indicate that the fabricated NiO//alpha-Fe2O3 based supercapacitor device has a great cycle performance with 85% capacitance retention under 10,000 cycles. This work may help to open up new areas for fabrication of lightweight and low-cost materials for energy storage systems. (C) 2016 Elsevier B.V. All rights reserved.
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