Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 16, Pages 7345-7349Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c02232
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Funding
- JSPS KAKENHI [JP17K19126, JP15H05839, JP16H01040, JP18H04271]
- JSPS [JP19J13174]
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A method for catalytic conversion of C(aryl)-C(alkenyl) bonds in styrene derivatives to new C-C bonds is developed. In the presence of a rhodium catalyst, the alkenyl groups of styrenes bearing a pyrazolyl directing group were efficiently converted to other carbon substituents upon reacting with various alkenes including styrenes, aliphatic alkenes, and allyl alcohols. It is also indicated that the C-C bond cleavage proceeded via a hydrometalation/beta-carbon elimination pathway.
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