Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 22, Pages 9938-9943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c04456
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Funding
- JSPS KAKENHI [JP18H01971, JP17H06449, JP18K05135]
- Kanazawa University SAKIGAKE Project 2018
- JST, PRESTO Grant [JPMJPR19T2]
- Tokyo Biochemical Research Foundation
- TOBE MAKI Scholarship Foundation
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The generation of tertiary, secondary, and primary alkyl radicals has been achieved by the direct visible-light excitation of a boracene-based alkylborate. This system is based on the photophysical properties of the organoboron molecule. The protocol is applicable to decyanoalkylation, Giese addition, and nickel-catalyzed carbon-carbon bond formations such as alkyl-aryl cross-coupling or vicinal alkylarylation of alkenes, enabling the introduction of various C(sp(3)) fragments to organic molecules.
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