Journal
CHEMICAL ENGINEERING JOURNAL
Volume 283, Issue -, Pages 1203-1209Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2015.08.029
Keywords
MCM-41; Hydrophobic environment; Trap for ethinyl estradiol; Mesoporous cavities
Categories
Funding
- CNPq
- CAPES
- FAPEMIG
- Centro de Microscopia/UFMG
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In this work, mesoporous hydrophobic cavities produced by a micelle structured CTAB (cetyl trimethylammonium bromide) trapped inside MCM-41 pores were used for the efficient removal of the hazardous hormone contaminant ethinyl estradiol (EE) present in water. The MCM-41 structure was prepared using different CTAB/Si molar ratios, i.e. 0.07, 0.12, 0.17, and 0.27. TG, SEM, TEM, BET, IR, elemental analysis, contact angle and positron annihilation spectroscopy showed that the MCM-41 silica structure is completely filled with trapped CTAB molecules (47-58 wt%) which results in no porosity and very low surface areas of 1-5 m(2) g(-1). These materials showed high efficiency to remove EE from aqueous solution whereas pure MCM-41 (without CTAB) with high porosity and a surface area of 1333 m(2) g(-1) showed no adsorption. These results are discussed in terms of EE sorption into the hydrophobic environment created by the CTAB trapped molecules inside the mesoporous cavities of MCM-41. (C) 2015 Elsevier B.V. All rights reserved.
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