Journal
CHEMICAL ENGINEERING COMMUNICATIONS
Volume 204, Issue 1, Pages 134-139Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00986445.2016.1245185
Keywords
Complete adsorption isotherm; Correct calculation; Freundlich exponent n; Inconsistency error; Separation factor; Thermodynamic parameter
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This article aims to discuss (1) the misconception about the Freundlich exponent n, (2) the important role of presenting the complete adsorption isotherms, (3) the inaccurately cited information compared to the original papers, (4) misconception regarding calculation of adsorption thermodynamic parameters, (5) and invalid conclusions regarding the separation factor. The inconsistency errors between adsorption equilibrium data and the thermodynamic parameters were also discussed. Furthermore, the adsorption process cannot reach equilibrium with the low initial Methylene Blue concentrations (50-250mg/L) at the solid/liquid ratio of 4g/L, which results in invalid arguments and conclusions regarding the adsorption isotherm.
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