Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 124, Issue 23, Pages 4774-4780Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcb.0c02544
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Funding
- Uppsala University
- Swedish Research Council [2019-05012]
- Swedish National Strategic e-Science program eSSENCE
- Swedish Research Council [2019-05012] Funding Source: Swedish Research Council
- Vinnova [2019-05012] Funding Source: Vinnova
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Deviations from the Nernst-Einstein relation are commonly attributed to ion-ion correlation and ion pairing. Despite the fact that these deviations can be quantified by either experimental measurements or molecular dynamics simulations, there is no rule of thumb to tell the extent of deviations. Here, we show that deviations from the Nernst-Einstein relation are proportional to the inverse viscosity by exploring the finite-size effect on transport properties under periodic boundary conditions. This conclusion is in accord with the established experimental results of ionic liquids.
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