Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 90, Pages 13265-13268Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07520g
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- Deutsche Forschungsgemeinschaft (DFG)
- Leopoldina Nationale Akademie der Wissenschaften
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The first hybrid crown ether with two adjacent disilane fragments was synthesized through reaction of O(Si2Me4Cl)(2) (3) with O(C2H4OH)(2). By means of DFT calculations, the complexation ability of 1,2,4,5-tetrasila[12] crown-4 (7) towards Li+ was determined to be considerably higher compared to [12]crown-4.
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