Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 62, Pages 9691-9694Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc02291j
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Funding
- Skoltech-MIT Center for Electrochemical Energy Storage
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- China Clean Energy Research Center-Clean Vehicles Consortium
- US Department of Energy [DE-PI00000012]
- Toyota Motor Europe
- US Department of Defense
- Samsung Advanced Institute of Technology (SAIT)
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Charging kinetics and reversibility of Na-O-2 batteries can be influenced greatly by the particle size of NaO2 formed upon discharge, and exposure time (reactivity) of NaO2 to the electrolyte. Micrometer-sized NaO2 cubes formed at high discharge rates were charged at smaller overpotentials compared to nanometer-sized counterparts formed at low rates.
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