4.7 Article

A simple strategy to the side chain functionalization on the quinoxaline unit for efficient polymer solar cells

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 42, Pages 6881-6884

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01771a

Keywords

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Funding

  1. National Natural Science Foundation of China [51173206, 21161160443, 21506258]
  2. Project of Innovation-driven Plan in Central South University, China [2016CX035]

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A new tetrafluoridequinoxaline electron accepting block from a quinoxaline core, which is substituted with a fluorine atom onto its backbone and side chains, was designed. A new copolymer (PBDTT-ffQx) was synthesized from tetrafluoridequinoxaline and benzodithiophene. The copolymer was characterized in detail. The photovoltaic properties were well investigated. A high PCE of 8.6% based on the single junction device was obtained.

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