4.7 Article

Synthesis of figure-of-eight helical bisBODIPY macrocycles and their chiroptical properties

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 71, Pages 10727-10730

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05439k

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Funding

  1. JSPS KAKENHI Grant [JP15H00723, JP15H00914]

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A macrocyclic bisBODIPY (bis(boron-dipyrromethene)) complex [1B(2)] with a figure-of-eight helicity was synthesized and successfully resolved. [1B(2)] was proven to be one of the most efficient red-emitting CPL (circularly polarized luminescence) fluorophores reported to date (lambda = 663 nm, vertical bar g(lum)vertical bar = 9 x 10(-3), phi(F) = 0.58).

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