4.7 Article

NHPI and palladium cocatalyzed aerobic oxidative acylation of arenes through a radical process

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 7, Pages 1416-1419

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08945j

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Funding

  1. National Basic Research Program of China (973 Program) [2015CB856600]
  2. National Natural Science Foundation of China [21325206, 21172006]
  3. National Young Top-notch Talent Support Program

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The NHPI and palladium cocatalyzed radical oxidative acylation of arenes with aldehydes and alcohols as acyl equivalents via selective C-H functionalization has been described. Molecular oxygen, the most environmentally friendly oxidant, was used as the terminal oxidant in this catalytic cycle.

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