Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 89, Pages 13151-13154Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07885k
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Funding
- Thousand Youth Talents Plan
- Shanghai Jiao Tong University
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An efficient and convenient method has been developed to achieve direct silylation of unactivated remote primary or secondary C(sp(3))-H bonds to form C-Si bonds with hexamethyldisilane (HMDS). This method highlights the emerging strategy to transform unactivated methyl or methylene into versatile functional groups in organic synthesis and provides a new method to construct functionalized C-Si bonds for synthetic chemistry.
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