Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 7, Pages 1338-1341Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08736h
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Funding
- Indian Institute of Technology Kanpur [IITK/CHM/20130187]
- DAE-BRNS [BRNS/CHM/2014110]
- CSIR
- Johnson Matthey
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An efficient, scalable, atom-economical, regio-selective air stable Cp*Co(III) catalyzed C-H and C-O coupling via a C-H activation/oxygen atom transfer reaction of quinoline N-oxide and an internal alkyne is reported. Such a catalytic transformation is witnessed for the first time with a cobalt catalyst and using N-oxide as a traceless directing group, in contrast to the existing literature. The developed synthetic methodology is straightforward and possesses various functional group tolerances, including heterocycles.
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