Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 32, Pages 5565-5568Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01107a
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Funding
- Russian Science Foundation [14-13-00060]
- Russian Foundation for Basic Research [16-33-60063, 16-33-60133]
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Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk(2))(2)] (X = Cl, Br). The HI2C-I center dot center dot center dot eta(1)((Pt)) halogen bonding and the bifurcated HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I center dot center dot center dot eta(2)((Pt-Cl)) reversible arrow HI2C-I center dot center dot center dot eta(1)((Pt)) transformation - were observed and confirmed theoretically.
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