Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 12, Pages 8000-8012Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00817
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Funding
- SERB, New Delhi, India [CRG/2018/000096]
- IISc, Bengaluru
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An efficient and novel route for assembling pyrrolo/piperido[1,2-a]indoles is portrayed involving a radical-mediated reductive epoxide opening reaction of N-tethered epoxy-indoles that trigger facile intramolecular cyclization followed by an oxidative quenching step. Capitalizing on the operational simplicity of the method involving just two steps and use of an efficient C-C bond-forming reaction, this radical-based protocol enables the modular assembly of an important class of N-fused indole derivatives with versatile functional and structural diversity.
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