Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 10, Pages 6697-6708Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00712
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Funding
- SERB, India [2016/4812]
- CSIR, India
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Highly robust one-pot, four-component cascade cyclization reaction of alpha-keto aldehydes, anilines, activated alkynes, and aromatic nucleophiles is developed to synthesize a diverse range of pharmaceutically important penta-substituted pyrroles. The reaction proceeds through the cascade cyclization of acylimines (in situ formed) with activated alkynes and aromatic nucleophiles such as indoles, pyrroles, and naphthols at room temperature under calcium(II) catalysis with high yields and broad substrate diversity.
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