Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 8, Pages 5220-5230Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b03272
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Funding
- Foundation of the Department of Education of Guangdong Province [2017KZDXM085, 2018KQNCX272, 2018KZDXM070]
- Science Foundation for Young Teachers of Wuyi University [2019td06, pdjh2019b0498]
- Chemical Industry Collaborative Innovation Center of Yueshan Town [368]
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A novel and efficient oxidative esterification for the selective synthesis of alpha-ketoesters and esters has been developed under metal-free conditions. In the protocol, various alpha-ketoesters and esters are available in high yields from commercially available ketones and potassium xanthates. Mechanistic studies have proven that potassium xanthate not only promotes oxidative esterification but also provides an alkoxy moiety for the reaction, which involves the cleavage and reconstruction of C-O bonds.
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