Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 85, Issue 8, Pages 5516-5524Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00277
Keywords
-
Categories
Funding
- SERB,New-Delhi [EMR/2016/006358]
- Indian Institute of Science
- R. L. Fine Chem
Ask authors/readers for more resources
A weakly coordinating carbonyl-directed coupling of allyl alcohols at the C-4 position of indole derivatives under the C-H activation conditions catalyzed by Rh(III) is reported. This results in alkylation at the C-4 position of indole derivatives exclusively. The obtained product forms a tricyclic derivative under aldol reaction conditions, which can be a potential precursor for synthesizing a few alkaloid molecules such as ergot, hapalindole alkaloids, and related heterocyclic compounds.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available