4.7 Article

Control of interpenetration in a microporous metal-organic framework for significantly enhanced C2H2/CO2 separation at room temperature

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 17, Pages 3494-3496

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10598f

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Funding

  1. Welch Foundation [AX-1730]
  2. National Natural Science Foundation of China [21436010, 21376205]
  3. Lin Guangzhao & Hu Guozan Graduate Education International Exchange fund

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A novel non-interpenetrated three-dimensional porous metal-organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions. The resulting UTSA-68a shows a notably higher porosity and adsorption selectivity (3.5-5) for C2H2/CO2 separation compared to that of doubly interpenetrated ZJU-30a (1.7-2.4) at room temperature.

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