Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 26, Pages 4796-4799Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00711b
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Funding
- National Natural Science Foundation of China [21276105]
- Fundamental Research Funds for the Central Universities [JUSRP51314B, JUSRP51513]
- project for Jiangsu scientific and technological innovation team
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An effective single crystal to single crystal transformation from a tetrahedral Ni cage to an FeNi cage was demonstrated. The iron(II) centers of the FeNi cage can be induced to display spin crossover behaviors with an increasing amount of Fe(II) ions. The SCSC metal-center exchange provides a powerful approach to modify solid magnetic properties.
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