4.7 Article

A highly sensitive electrochemiluminescence biosensor for the detection of organophosphate pesticides based on cyclodextrin functionalized graphitic carbon nitride and enzyme inhibition

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 28, Pages 5049-5052

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10491b

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Funding

  1. NNSF of China [21275119, 21575116, 51473136]
  2. Natural Science Foundation of Chongqing City [CSTC-2014JCYJA20005]
  3. Doctor Foundation of Southwest University [swu113029]
  4. Fundamental Research Funds for the Central Universities, China [XDJK2013C115, XDJK2015A002]

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A signal on an electrochemiluminescence (ECL) biosensor using beta-cyclodextrin (CD) functionalized graphitic carbon nitride (g-C3N4) as the luminophore was constructed for sensitive organophosphate pesticides (OPs) detection based on the enzyme inhibition of OPs, showing that the consumption of coreactant triethylamine (Et3N) decreased with a lessening of the acetic acid (HAc) in situ generated by enzymatic reaction.

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