4.7 Article

A MOF-derived Co-CoO@N-doped porous carbon for efficient tandem catalysis: dehydrogenation of ammonia borane and hydrogenation of nitro compounds

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 49, Pages 7719-7722

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03149h

Keywords

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Funding

  1. NSFC [21371162, 51301159, 21521001]
  2. 973 program [2014CB931803]
  3. NSF of Anhui Province [1408085MB23]
  4. Recruitment Program of Global Youth Experts
  5. Fundamental Research Funds for the Central Universities [WK2060190026, WK2060190065]

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The one-step pyrolysis of a zeolite-type metal-organic framework, Co(2-methylimidazole)(2) (ZIF-67), produces an N-doped porous carbon incorporating well-dispersed Co/CoO nanoparticles, which exhibit excellent catalytic activity, chemoselectivity and magnetic recyclability for the tandem dehydrogenation of ammonia borane and hydrogenation of nitro compounds at room temperature.

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