Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 18, Pages 3690-3693Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10221a
Keywords
-
Categories
Funding
- NSF CAREER award [CHE-1056657]
- Cottrell Scholar Award from the Research Corporation for Scientific Advancement
- Alfred P. Sloan Foundation
- Camille Dreyfus Teacher-Scholar Award from the Camille and Henry Dreyfus Foundation
- NSF MRSEC program [DMR-1120296]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1056657] Funding Source: National Science Foundation
Ask authors/readers for more resources
We explore the crystallization of a high surface area imine-linked two-dimensional covalent organic framework (2D COF). The growth process reveals rapid initial formation of an amorphous network that subsequently crystallizes into the layered 2D network. The metastable amorphous polymer may be isolated and resubjected to growth conditions to form the COF. These experiments provide the first mechanistic insight into the mechanism of imine-linked 2D COF formation, which is distinct from that of boronate-ester linked COFs.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available