4.7 Article

An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 30, Pages 5238-5241

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00189k

Keywords

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Funding

  1. NSFC [21475078, 21271120, 21201112]
  2. 973 Program [2012CB821705, 2013CB933800]
  3. Taishan Scholar's Construction Project

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The Cu4I4-MOF-based mixed matrix membranes (MMMs) can be readily prepared by one-step in situ self-assembly of a tri-armed oxadiazole-bridged ligand and CuI in polymer binder solution under ambient conditions. The visual and luminescent HCl(g) sensing detecting limits of the resulting Cu4I4-MOF-based MMMs are 3.2 and 1.6 ppb, respectively, and the response time is less than 1 min.

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