4.7 Article

Photochromic switching behaviour of donor-acceptor Stenhouse adducts in organic solvents

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 93, Pages 13576-13579

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc08079k

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Funding

  1. Australian Research Council [DP160100870]
  2. University of New South Wales
  3. Collaborative Access Program [MXCAP11195/11572]

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We report photochromic donor-acceptor Stenhouse adducts (DASAs) capable of fully reversible photoisomerization with visible light in organic solvents including chloroform, acetonitrile and benzene. The rates of photoisomerization and thermal reversion can be tuned by altering the electronics of the donor adduct. X-Ray crystallography and photo-NMR experiments unambiguously establish molecular structures.

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