Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 24, Pages 4470-4473Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10464e
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Funding
- National Natural Science Foundation of China [21462017, 21372251, 21373027]
- China Postdoctoral Science Foundation [2014M560649]
- Hunan Provincial Natural Science Foundation of China [2015JJ2113]
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A novel copper-catalyzed aerobic oxidative cyclization of benzamides via meta-selective C-H tert-alkylation using AIBN and analogues as radical precursors was described. This strategy provides an elusive and rapid means to 7-tert-alkylated isoquinolinediones, as well as the construction of tertiary alkyl-aryl C(sp(3))-C(sp(2)) bonds with positional selectivity.
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