Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 79, Pages 11744-11747Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05130h
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Funding
- Research Grants Council of the Hong Kong Special Administrative Region, China [T23-713/11]
- Japan Science and Technology Agency (JST)
- ERATO
- Adachi Molecular Exciton Engineering Project
- International Institute for Carbon Neutral Energy Research - Ministry of Education, Culture, Sports, Science and Technology (MEXT) [WPI-I2CNER]
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We applied organic nanostructures based on thermally activated delayed fluorescent (TADF) emitters for singlet oxygen generation. Due to the extremely small energy gaps between the excited singlet states (S-1) and triplet states (T-1) of these heavy-metal-free organic nanostructures, intersystem conversion between S-1 and T-1 can occur easily. This strategy also works well for exciplex-type TADF emitters prepared by mixing suitable donors and acceptors which have no TADF characteristics themselves.
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