4.7 Article

A N-heterocyclic tetracarbene Pd(II) moiety containing a Pd(II)-Pb(II) bimetallic MOF for three-component cyclotrimerization via benzyne

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 69, Pages 10505-10508

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04570g

Keywords

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Funding

  1. NSFC [21475078, 21271120]
  2. 973 Program [2012CB821705, 2013CB933800]
  3. Taishan Scholar's Construction Project
  4. Jilin Province Key Laboratory of Organic Functional Molecular Design Synthesis [130028653]

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A novel Pd(II)-Pb(II) bimetallic metal-organic framework Pd(II)-Pb(II)-MOF (B) which contains an N-heterocyclic tetracarbene Pd(II) moiety was synthesized based on a chelating N-heterocyclic dicarbene Pd(II)-NHDC ligand (A) under solvothermal conditions. It can be a highly active heterogeneous catalyst for three-component cyclotrimerization via benzyne species.

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