Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 69, Pages 10505-10508Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04570g
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Funding
- NSFC [21475078, 21271120]
- 973 Program [2012CB821705, 2013CB933800]
- Taishan Scholar's Construction Project
- Jilin Province Key Laboratory of Organic Functional Molecular Design Synthesis [130028653]
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A novel Pd(II)-Pb(II) bimetallic metal-organic framework Pd(II)-Pb(II)-MOF (B) which contains an N-heterocyclic tetracarbene Pd(II) moiety was synthesized based on a chelating N-heterocyclic dicarbene Pd(II)-NHDC ligand (A) under solvothermal conditions. It can be a highly active heterogeneous catalyst for three-component cyclotrimerization via benzyne species.
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