Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 69, Pages 10559-10562Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04790d
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Funding
- European Union (European Social Fund - ESF)
- Greek national funds through the Operational Program Education and Lifelong Learning of the National Strategic Reference Framework (NSRF) [ARISTEIA II - 4862]
- EnTeC FP7 Capacities programme [REGPOT-2012-2013-1, 316173]
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A novel NbO-type MOF is reported based on a palladated organic linker, showing a remarkable gravimetric and volumetric CO2 uptake, reaching 201.8 cm(3) g(-1) (9.0 mmol g(-1), 39.7 wt%) and 187.8 cm(3) cm(-3) at 273 K and 1 bar, respectively. Accurate theoretical calculations revealed that the exceptional CO2 uptake is due to the combination of Lewis base Pd(II)-CO2 (24.3 kJ mol(-1)) and Lewis acid Cu(II)-CO2 (30.3 kJ mol(-1)) interactions, as well as synergistic pore size effects.
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