Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 34, Pages 5796-5799Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01705c
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Funding
- JSPS [26810031]
- Grants-in-Aid for Scientific Research [26102013] Funding Source: KAKEN
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The organometallic Ru molecular wires 1-3 Ru(PR3)(4)(C CC5H5N)(2) [(PR3)(4) = (dppe)(2) (1), [P(OMe3)](4) (2), and (dmpe)(2) (3)] show significantly higher conductance compared to their organic counterpart, 1,4-dipyridyl butadiyne (4). CV and UV-Vis measurements and DFT calculations suggest that the high-lying HOMOs of the Ru wires are the key factor for the high conductance.
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