Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 97, Pages 13955-13958Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07105h
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Funding
- National Natural Science Foundation of China [21072044, 21672052]
- Henan province [14IRTSTHN006, 152300410057, 162300410002]
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An organocatalytic asymmetric reaction of benzofuran-2(3H)-ones with naphthoquinones is disclosed. The current method provides a direct way to facilitate arylation of benzofuran-2(3H)-ones in high yields with excellent enantioselectivities. A cooperative visible light photocatalysis with asymmetric hydrogen-bond catalysis has also been developed, thus allowing the more widely available 1-naphthols instead of naphthoquinones to be applied to facilitate the arylation with satisfactory results (up to 95% ee).
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