4.7 Article

The synthesis of pyrroles and oxazoles based on gold alpha-imino carbene complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 46, Pages 7336-7339

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01742h

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Funding

  1. National Research Foundation of Korea (NRF), (Center for New Directions in Organic Synthesis) - Korean government [2014-011165, NRF-2014R1A2A2A01006060]
  2. UNIST (Ulsan National Institute of Science & Engineering) Research Fund [1.160001.01]
  3. Nanyang Technological University

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Cationic gold complexes of alpha-oximimino carbenes have been identified to react with weak nucleophiles including enol ethers and nitriles. These findings allowed us to develop the highly efficient synthesis of pyrroles and oxazoles.

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