Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 68, Pages 10407-10410Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc04109d
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Funding
- 973 Program [2011CB808600, 2012CB725302, 2013CB834804]
- National Natural Science Foundation of China [21390400, 21272180, 21302148, 91427303, 21402217]
- Chinese Academy of Sciences [KGZD-EW-T05]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Ministry of Science and Technology of China [2012YQ120060]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
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An oxidant-free dehydrogenative sulfonylation of alpha-methyl-styrene derivatives was developed for the construction of allylic sulfones by using eosin Y as a photosensitizer in conjunction with a cobaloxime catalyst. The process features a low-cost metal catalyst and atom economy, which provides an appealing strategy for future synthetic chemistry.
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