Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 31, Pages 5447-5450Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc01376g
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Funding
- Institute for Basic Science [IBS-R019-D1]
- National Science Foundation [CHE-1266323]
- BK21 Plus Program - Ministry of Education
- National Research Foundation of Korea
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The synthesis and study of a cyclic (alkyl)(amido) carbene is described. The carbene was found to undergo C-H insertion at low temperatures, formed cyclopropenes upon exposure to alkynes, and facilitated desulfurization reactions. Spectroscopic studies revealed that the carbene is strongly pi-accepting but retains a complimentary degree of sigma-donating properties.
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