Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 85, Pages 12602-12605Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc05097b
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Funding
- National Natural Science Foundation of China [21501065]
- Changbai Mountain Scholars Program [2013073]
- Science and Technology Program of Jilin Province [2016010319JC]
- Research on the Science and Technology of the Education Department of Jilin Province [2016220]
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A series of phenylene-based conjugated microporous polymers (CMPs) of the A(6) + M-x (x = 2, 3, 4, 6) type were synthesized. By tuning the monomer length and geometry, the BET surface area of CMPs can be tuned from 571 to 1115 m(2) g(-1). Amongst the synthesized CMPs, A(6)CMP-1 exhibits the highest CO2 adsorption capacity of 1218 mg g(-1) at 318 K and 60 bar pressure. In addition, A(6)CMP-4 shows a high selectivity ratio of 47 for CO2/N-2.
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