Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 8, Pages 1665-1668Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc08307a
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Funding
- SERB-DST, Government of India [SR/S1/OC/12/2012]
- AvH Foundation
- CSIR
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The temperature dependent selectivity switch in the reaction of arynes with aliphatic alcohols in THF has been reported. At -20 degrees C, arynes smoothly insert into the O-H bond of alcohols to form alkyl aryl ethers. Interestingly, at 60 degrees C, a highly selective multicomponent coupling occurs with the solvent THF acting as the nucleophilic trigger affording (4-(alkoxy)butoxy)arenes.
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