4.7 Article

From ACQ to AIE: the suppression of the strong pi-pi interaction of naphthalene diimide derivatives through the adjustment of their flexible chains

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 77, Pages 11496-11499

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc06176a

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Funding

  1. National Natural Science Foundation of China [21372003, 21325416, 51573140]
  2. National Fundamental Key Research Program [2013CB834701]

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Unlike normal ACQ-to-AIE conversion by the introduction of aromatic rotors accompanying the realization of a twisted conformation and a prolonged pi-system, in this communication, the adjustment of the flexible chains can reach this point with the tunable packing modes while the original pi-system core and related properties of the aromatic naphthalene diimide remain nearly unchanged, providing an alternative approach for the inhibition of unwanted pi-pi stacking.

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