4.7 Article

Tuning of molecular qubits: very long coherence and spin-lattice relaxation times

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 18, Pages 3623-3626

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00300a

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Funding

  1. Fonds der Chemischen Industrie

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We report a pulsed EPR study on different transition metal phthalocyanines, elucidating the dependence of spin relaxation on solvent, ligand and metal ion. Coherence times of >40 mu s and spin-lattice relaxation times of up to 2 s were found. Minimization of SOMO-environment overlap leads to increased coherence times.

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